Cloudy with a Chance of Iron: The Transition Between Spectral Types L and T Adam J. Burgasser U.C.L.A. The search for brown dwarfs has unveiled two new spectral classes, L and T dwarfs, the first additions to the main sequence in over 65 years. Substellar objects evolve through both spectral types as they cool, eventually becoming too faint to detect with current technology. We are now beginning to see that the transition between these two classes is complex, influenced by the rainoout of heavy metals (Fe, V, Ti) and dust grains, and modulated by cloud structure that may be heterogeneous and can vary over time. I present new results for late L dwarfs and early T dwarfs that highlight this transition, and discuss how the observations may be explained (or not!) in light of recent theoretical work. I also describe some of the implications of this transition on classification schemes and the local substellar mass function