Title: Probing the formation and processing of silicates with ISO and Spitzer Spectroscopy Francisca Kemper University of California, Los Angeles Abstract: Silicates are formed by evolved stars, in particular around asymptotic giant branch stars and red supergiants. ISO spectroscopy has revealed that in many cases silicates in circumstellar environments are found to have a high degree of crystallinity. Evolved stars eject their circumstellar material into the interstellar medium. The composition of interstellar silicates are studied by means of infrared absorption features, also observed with ISO, and it is found that the interstellar silicates are almost completely amorphous. I will discuss time scales and processes for the amorphization of crystalline silicates ejected by post-main-sequence stars. The formation process of silicates in the outflows of evolved stars is not understood. I will (hopefully) present Spitzer IRS spectroscopy of AGB stars in the LMC, of which the low metallicity can give us new insights in the processes involved in the formation of interstellar dust.