Title: Brown Dwarfs and Planetary-Mass Candidates in Upper Scorpius: A Test of Evolutionary Models through High-Resolution Spectral Analysis Subu Mohanty Harvard-Smithsonian Center for Astrophysics Abstract: We present an analysis of high resolution optical spectra for a sample of very young, mid- to late M, low-mass stellar and substellar objects in Upper Scorpius. Effective temperatures and gravities are derived from a multi-feature spectral analysis, through comparison with the latest synthetic spectra. We also calculate extinctions, radii and masses for our sample based on our temperatures and gravities, observed photometry, surface fluxes predicted by the synthetic spectra, and the known distance to Upper Sco. These estimates are INDEPENDENT of theoretical evolutionary models and isochrones. We also preform the same analysis for GG Tau B, for which stellar parameters have previously been estimated from isochrone comparisons. We compare all our results to the predictions of the BCAH98 evolutionary tracks. We show that for the coolest, lowest mass objects, significant discrepancies exist between the BCAH98 tracks and our results. For a given mass and age, the tracks predict smaller radii and larger temperatures than our values. Recent studies of low-mass eclipsing binary systems with very well determined masses, radii and luminosities show that the theoretical tracks indeed systematically underestimate radius and overestimate temperature. We propose that the same effect is responsible for the disagreement between our results and BCAH98's theoretical predictions. If so, it also implies that the uncertainties in the evolutionary tracks are enhanced for the coolest, lowest mass pre-Main Sequence (PMS) objects. In Upper Sco, we find two of our objects to be well within the planetary mass regime (~ 6 M_J). If we are correct, then these are the first planetary-mass objects to be confirmed cluster members through Lithium detection, and with masses determined independent of theoretical evolutionary tracks. Our result also raises the possibility that the some of latest spectral type PMS objects may be significantly lower in mass than a simple comparison to current isochrones might suggest. At the very least, both our objects are ultra-low mass ones, at the brown dwarf / planetary mass boundary. Their presence, combined with that of similar ultra-low mass isolated objects being found in other clusters, by different groups, raises the possibility that such objects are ubiquitous. How to form them remains a serious challenge to theory.