Astrophysical spectro-polarimetry: New developments Jan Stenflo Institute of Astronomy ETH Zurich With a new class of imaging polarimeters it is now possible to completely eliminate the previous main limiting factors of seeing and gain-table noise in the polarization images. This has allowed us to record solar spectra with high spectral resolution and a noise in the fractional polarization as low as 5 x 10^{-6}. At such levels of sensitivity the whole solar spectrum is polarized, also in the absence of magnetic fields. The polarized spectrum has a surprising structural richness displaying a multitude of new effects, like quantum interferences and optical pumping, which have been unfamiliar in an astrophysical context. The high sensitivity has also opened the door to a new class of magnetic-field diagnostic techniques based on the Hanle effect, which represents the influence of magnetic fields on the polarization that is produced by coherent scattering processes. While we are exploring this new world of polarization physics for the Sun we are in the process of developing and implementing a Stokes imaging polarimetry system based on this technology but to be used for night-time astronomy. Besides presenting an overview of the solar applications we report on first exploratory results with night-time imaging polarimetry and discuss its future possibilities and limitations